干渣吸附处理含磷污水的研究

采用批量平衡法，研究了水体磷浓度、干渣粒径和温度对干渣吸附除磷效果的影响，探讨了干渣对水体中磷素的选择性吸附特征及其饱和吸附磷素后的解吸释磷现象。结果表明，溶液浓度越高，干渣吸附除磷速率越慢，效率越低。磷浓度为6和12mg·L^-1时，作用20h后，除磷效率可达90%。干渣粒径越小，除磷速率越快，效果也越好，磷浓度为12mg·L^-1，吸附平衡后，30、60和100目干渣的除磷效率分别为80%、93%和96%。温度对干渣除磷效果的影响较大，磷浓度为12mg·L^-1，25和35℃时，除磷效率可达95%，但在5℃时，除磷效率仅为75%。干渣能够选择性地吸附去除水体中的磷素，适宜作为除磷吸附剂，处理多种含磷污水。     

改性木质素对砖红壤磷素有效性的影响

磷肥施入砖土壤后，土壤速效磷随着时间的推移，呈现下降的趋势。利用改性木质素缓释磷铵，可以有效地络合土壤活性钵，降低其活性，从而阻止土壤速效磷被固定，使土壤磷素维持在较高的水平。土壤中交换性钙和交换性镁对土壤速效磷的影响不大。     

Phosphorus Response and Fertilizer Recommendations for Wheat Grown on Nitisols in the Central Ethiopian Highlands

The provision of farmers with proper and balanced fertilizer recommendations is becoming increasingly important, for reasons of crop productivity, food security, and sustainability. Phosphorus (P) response trials with wheat were conducted on Nitisols at 14 sites in the central Ethiopian highlands during the 2010 and 2011 cropping seasons. The treatments, comprising six levels of P fertilizer (0, 10, 20, 30, 40, and 50 kg P ha^?1), were arranged in a randomized complete block design with three replicates. Based on a yield difference between the control and the P treatments, 90% of sites responded to P fertilizer. Application of P fertilizer increased wheat grain yield, up to 30% more than the control. Extractable soil P concentrations (Bray 2, 0–15 cm deep) 3 weeks after planting significantly responded to P fertilizer rate. The critical P concentration (for 90% relative yield) was 13.5 mg kg^?1. Most sites tested had Bray 2 P values <10 mg kg^?1. In the absence of a soil test, a recommendation of 40 kg P ha^?1, resulting in the best response overall, could be made for the first year of application. We also recommend that to prevent a potential loss of wheat yield, a maintenance application of at least 5–12 kg P ha^?1 be applied every year, irrespective of the calculated recommended rate, in order to replace P exported from the field in produce. Further field trials are required to determine interactions between P response and the effects of climate, soil properties, and other management practices.     

彭州市丹景山镇典型农作物输出系数研究

农业非点源污染具有随机性大、分布范围广、危害性大等特点,已成为重要的环境污染方式。根据现场实测,分析了四川省彭州市丹景山镇不同作物田的总氮、总磷输出系数,探讨了不同作物及不同典型水文年输出系数形成差异的原因,完善了输出系数模型,为控制丹景山镇农业氮素、磷素的输出提供建议。     

Distribution and Dynamics of Phosphorus in an Agricultural Watershed with a Long-Term History of Poultry Waste Application

The objective of this research is to investigate the effects of long-term broiler litter application on soil phosphorus (P) and water quality and examine the spatial variations of soil P at a private poultry farm in Mississippi. Results indicated that the littered soil had 86 times more Mehlich III–extractable P in the surface horizon compared to the nonlittered soil. When compared to the runoff from nonlittered soil, mean soluble phosphate (PO₄)-P concentrations in the littered soil's runoff were 85 times greater throughout the study. Mass loss of P from the littered field was significantly greater than from the nonlittered field, and it decreased with each sequential runoff event. There were no linear relationships between the spatial variations of litter application rates and the P spatial variability in the littered soil; however, the variations in soil P levels could be a result of the cumulative effects of more than 20 years of litter application.     

Effects of Carbofuran on Availability of Macronutrients and Growth of Tomato Plants in Natural Soils and Soils Amended with Inorganic Fertilizers and Vermicompost

The effects of lower field rate (LFR), field rate (FR), and higher field rate (HFR) applications of carbofuran on ammonium (NH₄)-nitrogen (N), nitrate (NO₃)-N, available phosphorus (P), and available potassium (K) contents in natural soils and those amended with inorganic fertilizers and vermicompost on the growth of tomato plants were studied. The NH₄-N, NO₃-N, available P, and available K contents increased up to FR but the most significant increase in was observed at LFR of carbofuran application. At HFR there was a significant reduction in nutrient availability. With passage of time all these parameters increase up to 30 days; thereafter, a decrease was observed up to the end of the experiment in both unamended and amended soils. The greater plant growth was observed at LFR of carbofuran application and at HFR the plants exhibited phytotoxicity in the form of marginal leaf scorching in both systems. The morphological growth parameters of tomato plants were positively correlated with nutrients availability.     

Correlation of Soil pH and Mehlich‐3 Phosphorus with Postflood Rice Phosphorus Concentrations in Arkansas

Abstract

Plant‐available phosphorus (P) measured by routine soil‐test methods is poorly correlated with rice grain yield in Arkansas. Our objective was to determine whether soil water pH (pH_w) and Mehlich‐3 P were correlated with growth and yield of rice grown on silt loam soils. Data from 35 field studies were used to correlate Mehlich‐3 P and pH_w with relative yield, dry matter accumulation, and P concentration at the midtillering stage. Significant linear or nonlinear relationships between pH_w or Mehlich‐3 P with rice growth parameters were delineated but explained less than 27% of the variability in dry matter and P concentrations at the midtillering stage and grain yield at maturity. Mehlich‐3 P and pH_w together explained 61% of the variability in midtillering P concentrations. Midtillering whole‐plant P concentrations were positively related to relative grain yield and dry matter production and will be used to identify soils with limited P availability for rice in Arkansas.     

Sulfur content of plant material: A comparison of methods of oxidation prior to determination

Abstract

Procedures for S determination involving digestion of plant material with HNO₃/HClO₄ mixtures gave lower values than those using oxygen flask combustion. Tests on a range of S compounds showed that the HNO₃/HClO₄ procedure underestimated S present in methionine, cysteine and glutathione but S in sulfate and the glucosinolate, sinigrin, was not underestimated.

Low recoveries using HNO₃/HClO₄ digestion procedures can be due both to incomplete oxidation of certain compounds and to gaseous losses during the vigorous boiling stage of digestion.     

Relationship between Olsen P and Ammonium Lactate–Extractable P in Portuguese Acid Soils

The soil phosphorus (P) test in Portugal is based on extraction with ammonium lactate (AL) at acidic pH. Because this test is rarely used in other countries, it is desirable to see whether the AL-P values correlate with the more commonly used P tests. In this work, we compared AL-P with bicarbonate-extractable P (Olsen's method) for a group of 48 samples from Portuguese acidic soils differing widely in P status. Despite their contrasting composition, both reagents extracted phosphate from the same sources, albeit in different proportions. Both Olsen P and AL-P were strongly correlated with resin-extractable and dilute electrolyte-desorbable P, which are respectively related to the soil contents in phytoavailable P and P that can be released to runoff or drainage water. Olsen P and AL-P were strongly correlated (R² = 0.870), the correlation became stronger when three overfertilized soils were excluded (Olsen P = 2.35 + 0.45 AL-P; R² = 0.908; P ≤ 0.001, n = 45). No correlation was observed for a group of soils recently fertilized with Gafsa phosphate probably because the acidic AL reagent dissolved residual calcium phosphate, thus overestimating the soil content in desorbable P. On the basis of the present results and the AL-P-based fertility classes used for fertilizer recommendation purposes, Olsen P–based fertility classes were tentatively proposed for Portuguese acidic soils.     

Effect of Cropping on Changes in Phosphorus Fractions of Soils from Arable and Other Forest Land Use: A Greenhouse Bioassay

Abstract

Laboratory and greenhouse studies were conducted on six soils from natural reserves, seven plantation soils, and two arable soils from the Omo biosphere reserves in southwestern Nigeria to assess the phosphorus (P) fractions and the extent to which the soils could support five consecutive cycles of maize (Zea mays L.) harvest. The organic‐P fractions constitutes about 50% of the total P, and the inorganic‐P fractions in the order of abundance was iron (Fe) P>occluded P>aluminum (Al)‐P>calcium (Ca) P. The residual P constituted about 20% of the total P. There were significant reductions in the inorganic‐P fractions after five consecutive maize harvests; this was however, more pronounced in the available P (Bray 1). About 62% reduction in Bray 1 P was recorded after maize harvests. The reductions in the P forms after five cycles of maize harvest was Bray 1 P>Ca P>residual P>Al P>total P>Fe P>organic P>occluded P>reductant P. The capacity of the soils to support maize growth without fertilization varied widely in each of the maize cycle. Soil from natural reserves produced a significantly higher maize yield compared to most plantation soils. The arable soils investigated were depleted of their fertility after the third crop harvest.